九龙江河口区表层水铀同位素的粒级分布          下载免费PDF全文

吕娥  张磊  陈敏  邱雨生  邢娜  杨伟锋  李艳平  黄奕普 《海洋学报》2007,29(4):59-68

利用微滤和超滤技术研究了九龙江河口区表层水中铀及其同位素组成的粒级分布和地球化学行为.结果表明,溶解态(<0.4μm)中低分子量组分(<10 000 u)占主要份额,胶体态(10 000 u~0.4μm)238U所占比例不足1%,且随盐度的增加其所占份额逐渐降低.溶解态、低分子量组分和胶体态238U的比活度与盐度之间存在良好的线性正相关关系,证实它们在九龙江河口区呈现保守行为.在颗粒态(>0.4μm)中,各粒级组分238U所占份额主要受控于相应颗粒物的浓度,在盐度小于20的区域,各粒级颗粒组分238U占颗粒态的份额有如下变化次序:10~53μm>2~10μm>0.4~2μm>大于53μm,而在盐度大于30的近外海站位,该次序发生一些变化:0.4~2μm>10~53μm>2~10μm>大于53μm,最小粒级颗粒组分238U的贡献有所增加,反映了自生铀贡献的加强.九龙江河口区表层水中溶解态(包括低分子量组分和胶体态)的234U/238U)_A.R.均大于1,显示出234U过剩的特征,而各粒级颗粒组分中的234U/238U)_A.R.则接近于平衡值(1.0).这一现象与陆地岩石风化过程中水体对铀的淋滤释出量及234U的优先浸出有关.对232Th/238U质量比的研究显示,溶解态及其所包括的低分子量组分和胶体态的232Th/238U质量比均小于1,而颗粒态及其所包括的4个粒级组分中的232Th/238U质量比均大于1,反映了向外海输送过程中铀、钍地球化学行为的差异.  相似文献   

Genesis and Metallogenic Process of the Lujing Uranium Deposit,Southwest Jiangxi Province,China: Constraints of Micropetrography and S–C–O Isotopes     

《Resource Geology》2018,68(3):303-325

The Lujing uranium deposit, located in the southeastern part of the Nanling metallogenic province, is one of the representative granite‐related hydrothermal uranium deposits in South China. Basic geology, geochemistry, and geochronology of the deposit have been extensively studied. However, there is still a chronic lack of systematic research on the genesis and metallogenic process of the deposit. Thus, we recently carried out an electron microprobe and stable isotopic analysis. The main research results and progresses are as follows: Uranium minerals in this deposit include coffinite, pitchblende, and uranothorite, and small amounts of uranium exist in accessory minerals in the form of isomorphism. Coffinite, which occurs predominantly as the pseudomorphs after pitchblende, also occurs as a primary mineral and is locally formed from the remobilization of uranium from adjacent uranium‐bearing minerals. The mineralizing fluid was originally composed of a magmatic fluid generated by late Yanshanian magmatism. The high As content of pyrite in ores may reflect the addition of meteoric water, or the formation water (or both), to the magmatic hydrothermal system. The δ³⁴S values vary from −14.4‰ to 13.9‰ (mean δ³⁴S = −3.9‰), showing a range that is similar to nearby Cambrian metamorphic strata and Indosinian granites, indicating that these host rocks represent the source of sulfur; however, the possibility of a mantle source cannot be completely ruled out. According to our new isotopic data and recent Pb isotopic data, we conclude that the uranium in ores was derived by leaching dominantly from the uranium‐rich host rocks, especially the Cambrian metamorphic strata. The δ¹³C_PDB values (−8.75‰ to 1.40‰; mean δ¹³C_PDB = −5.41‰) and δ¹⁸O_SMOW values (5.45–18.62‰; mean δ¹⁸O = 13.02‰) of reddish calcite from the ore‐forming stage suggest that the CO₂ in the mineralizing fluids was derived predominantly from the mantle, with a small component contributed by marine carbonates. Based on these new data and previous research results, this paper proposes that uranium metallogenesis in the Lujing deposit is closely associated with mafic magmatism resulting from crustal extension during the Cretaceous to Paleogene in South China.  相似文献   

准噶尔盆地东北部侏罗系砂岩型铀矿成矿环境与找矿方向探讨     

何中波  秦明宽  宋继叶  郭强  许强  刘章月  杨烨  黄少华 《矿床地质》2018,37(1):175-190

文章从蚀源区铀源条件、中新生代构造演化条件、侏罗系沉积建造特征及后生蚀变特征等角度分析了准噶尔盆地东北部砂岩型铀矿的区域成矿条件,认为卡拉麦里山的富铀花岗岩体为该区砂岩型铀成矿提供了丰富的铀源,中侏罗统含煤碎屑岩建造为砂岩型铀成矿提供了良好的容矿空间,侏罗纪以来多期次不整合面的发育为含铀含氧水的渗入改造提供了通道及时间,为大规模层间氧化带的发育提供了物质基础。研究结果显示,卡拉麦里山北坡为最有利的砂岩型铀矿找矿部位,其主要找矿目标层位为中侏罗统头屯河组,找矿类型为层间氧化带型。  相似文献   

甘肃省龙首山芨岭铀矿床成矿热液流体特征研究     

赵如意  王博  陈毓川  王刚  陈云杰  聂利  李涛 《地球学报》2018,39(3):282-294

芨岭铀矿是中国北方最典型的钠交代型铀矿床之一,文章通过对芨岭矿床ZKJ9-4钻孔深部所见含矿蚀变闪长岩、近矿蚀变闪长岩、远矿蚀变闪长岩、闪长岩原岩地球化学特征和组分迁移计算及矿体中心部位的淡粉红色方解石脉流体包裹体特征、均一温度、盐度和激光拉曼光谱研究,认为芨岭钠交代型铀矿床的成矿流体含有大量碳酸铀酰络合物[UO_2(CO_3)_2]~(2–)和[UO_2(CO_3)_2]~(4–)的同时还含有丰富的SiO_2、Na~+、Ca~(2+)、Mg~(2+)、Fe~(2+)、Mn~(2+)、∑REE、U、Th、Ga、Sr、Zr、Ba、Rb、Nb、Mo、Cd、Sn、Hf、Ti、Ta、CO_2、H_2S和CH_4等组分,成矿流体具有较强的还原性,并对MnO、K_2O、Cr和Co具有较强的交代溶蚀作用。成矿流体是起源于岩浆演化晚期的再平衡岩浆水,热液温度为(300±20)℃,盐度为2.99 wt%~4.57 wt%NaCl,密度为0.75~0.77 g/cm~3。流体沸腾是芨岭钠交代型铀矿成矿物质的早期卸载机制,晚期成矿流体中加入了大量的大气降水,流体混合作用进一步促进了成矿物质的卸载。  相似文献   

纳米比亚湖山铀矿地质特征、控矿因素及其成因探讨   总被引：1，自引：0，他引：1  

张怀峰  陆建军 《世界地质》2018,37(1):105-123

湖山铀矿位于泛非期达马拉造山带的南部中央区带内,构造以NNE-SSW向穹窿和断裂为主。矿区内地层自老至新为艾杜西斯组、可汗组、罗辛组、楚斯组、阿兰蒂斯组、卡里比布组和卡塞布组,侵入岩为寒武纪至晚新元古代花岗岩类。晶质铀矿为主要原生矿石矿物。后期热液叠加导致了铀石、硅钙铀矿和黄硅钾铀矿等热液矿物的形成以及高岭土化、蛇纹石化、绢云母化和绿泥石化等蚀变作用。矿床的形成受矿区地层、岩浆岩和构造联合控制,矿化仅发生于D和E型花岗岩内。矿化岩体呈席状侵入于NNE-SSW向湖山背斜转折端和翼部高应力区域,赋存于罗辛组与可汗组不整合接触带及其上部的罗辛组,少量赋存于楚斯组内。矿区内构造-岩浆事件可划分为四个阶段,铀成矿作用与第四阶段构造-岩浆事件密切相关,含矿D和E型花岗岩为后造山伸展环境下富铀阿巴比斯基底重熔形成。  相似文献   

哈萨克斯坦楚—萨雷苏盆地砂岩型铀矿床地质—伊犁盆地蒙其古尔铀矿床含矿砂岩成岩蚀变特征及其有机-无机流体成岩成矿效应     

丁波  刘红旭  李平  张虎军  张宾  潘澄雨  张晓 《地质论评》2018,64(1):149-164

伊犁盆地蒙其古尔铀矿床为典型的层间氧化带型铀矿床,虽然前人对该区铀矿的成矿流体进行了较为系统的研究,但对其成矿流体来源依然存在较大的分歧,尤其对该区成矿流体与蚀变特征、铀成矿的内在联系研究较少。本文为了研究蒙其古尔铀矿床成矿流体来源及其与成岩蚀变、铀成矿的内在联系,综合地应用了偏光显微镜、扫描电镜、电子探针等手段,对其含矿目的层砂岩成岩蚀变进行系统的分析,并对蚀变矿物高岭石H—O同位素、碳酸盐胶结物C—O同位素及黄铁矿S同位素进行了研究。研究表明：与砂岩型铀矿有关的成岩蚀变类型主要有黏土化、碳酸盐化、硅化及金属矿化;成矿流体中水δDH2O,V SMOW为-48.3‰～-93‰, δ18OH2O,V SMOW为-10.3‰～-5.1‰,碳酸盐胶结物δ13CV PDB为-10.9‰～-7.2‰,δ18OV SMOW为176‰～249‰,黄铁矿δ34SV CDT为-17.3‰～12‰,上述特征揭示蒙其古尔铀矿床成矿流体是由大气降水性质的地表水（无机）和煤系地层有机质脱羟基及热降解作用产生的有机酸及CH4等还原性气体（煤层气）（有机）两部分组成;成岩蚀变和铀成矿效应皆是有机—无机流体及流体与周围砂岩相互作用的结果。  相似文献   

Dual Control of Depositional Facies on Uranium Mineralization in Coal‐bearing Series: Examples from the Tuanyushan Area of the Northern Qaidam Basin,NW China     

GUO Biao  SHAO Longyi  WEN Huaijun  HUANG Guangnan  ZOU Mingjun  LI Yonghong 《《地质学报》英文版》2018,92(2):733-754

The uranium deposits in the Tuanyushan area of northern Qaidam Basin commonly occur in coal-bearing series. To decipher the U-enrichment mechanism and controlling factors in this area, a database of 72 drill cores, including 56 well-logs and 3 sampling wells, was examined for sedimentology and geochemistry in relation to uranium concentrations. The results show that coal-bearing series can influence uranium mineralization from two aspects, i.e., spatial distribution and dynamic control. Five types of uranium-bearing rocks are recognized, mainly occurring in the braided river and braided delta sedimentary facies, among which sandstones near the coals are the most important. The lithological associations of sandstone-type uranium deposits can be classified into three subtypes, termed as U-coal type, coal-U-coal type, and coal-U type, respectively. The coal and fine siliciclastic rocks in the coalbearing series confined the U-rich fluid flow and uranium accumulation in the sandstone near them. Thus, the coal-bearing series can provide good accommodations for uranium mineralization. Coals and organic matters in the coal-bearing series may have served as reducing agents and absorbing barriers. Methane is deemed to be the main acidolysis hydrocarbon in the U-bearing beds, which shows a positive correlation with U-content in the sandstones in the coal-bearing series. Additionally, the δ13 C in the carbonate cements of the U-bearing sandstones indicates that the organic matters, associated with the coal around the sandstones, were involved in the carbonation, one important component of alteration in the Tuanyushan area. Recognition of the dual control of coal-bearing series on the uranium mineralization is significant for the development of coal circular economy, environmental protection during coal utilization and the security of national rare metal resources.  相似文献   

桂北376铀矿床烃气地球化学研究     

莫连 《地质与勘探》2023,59(5):1027-1042

烃气测量法在锡、金、铜、铅锌等金属矿床找矿中得到了广泛应用,而该技术在花岗岩型铀矿找矿中的应用鲜有报道。本文对桂北376铀矿床已知矿体开展了烃气测量试验,结果显示：相较于其他金属矿,该铀矿区花岗岩和土壤中总烃含量极低,而且花岗岩总烃含量(平均19.42μL/kg)高于上覆土壤(平均6.32μL/kg)。花岗岩中U与多数烃气组分呈负相关,与重烃呈正相关,重烃在U迁移过程中作用强于轻烃;花岗岩烃气标准化配分模式以C₁、iC₄和C₂^-正异常为特征;铀矿化程度与iC₄/nC₄、(C₁+iC₄+C₂^-)/(C₂+C₃+nC₄)及C₂^-/C₃^-比值呈正相关,与C₂₊/∑C比值呈负相关等可为寻找铀矿提供依据。3...  相似文献   

建场测深法在新疆布尔津盆地油铀勘探中的应用     

白诗筠 《地质与勘探》2023,59(5):1054-1064

为明确位于新疆北部的布尔津盆地的资源状况,以实际采集数据为基础,采用建场测深法成果剖面研究了该盆地的地层地质结构,并对深层油气及浅部砂岩型铀矿进行评价。通过利用已知测井电阻率曲线模拟计算不同深度的电磁信号频率响应,论证了该方法探测从浅层第三系到深部石炭系的采集参数和工作方案;在数据处理成果的基础上,结合研究区已知地层物性特征,推断沿线的地质结构,揭示了布尔津凹陷的结构及下二叠统卡拉岗组、上石炭统哈尔加乌组、上石炭统恰其海组地层的分布,认为哈尔加乌组是本区有潜力的烃源岩。同时利用电阻率及双频相位属性对研究区浅部第三系砂岩型铀成矿条件进行分析,其结果与附近已知矿点情况吻合。本文提出的方法可为类似地区进行多种矿产资源勘探提供技术参考。  相似文献   

鄂南彬州—双龙地区断裂特征与铀成矿关系探讨     

刘坤鹏  于宏伟  武正乾  冯博  刘凯鹏  李卫 《地质论评》2023,69(Z1):171-174

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